| 以冠醚为骨架的多足配体稀土配合物的合成、表征及荧光性质研究 |
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| 引用本文： | 柳佃义,闫旭焕,唐 瑜,刘伟生,谭民裕. 以冠醚为骨架的多足配体稀土配合物的合成、表征及荧光性质研究[J]. 无机化学学报, 2008, 24(8): 1356-1359 |
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| 作者姓名： | 柳佃义 闫旭焕 唐 瑜 刘伟生 谭民裕 |
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| 作者单位： | 兰州大学化学化工学院,功能有机分子化学国家重点实验室,兰州,730000 |
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| 基金项目： | 国家自然科学基金 , 教育部新世纪优秀人才支持计划 , 甘肃省自然科学基金 |
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| 摘 要： | A novel podand ligand using crown ether as skeleton and N-benzylsalicylamide as functional arms, 4,5-bi{2′-methylbenzeneaminoformyl)phenoxyl]methyl}-benzo-12-crown-4 (L), and its rare earth nitrate complexes have been synthesized. These complexes were characterized by elemental analysis, conductivity measurements and IR spectroscopy. Spectrographic analyses suggest that the complexes show a similar coordination mode. At the same time, the luminescent properties of the Eu(Ⅲ) and Tb(Ⅲ) complexes were also studied.
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| 关 键 词： | 多足配体； 冠醚； 稀土配合物； 荧光性质 |
Synthesis, Characterization and Luminescent Properties of Rare Earth Complexes with Podand Ligand Using Crown Ether as Skeleton |
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| LIU Dian-Yi,YAN Xu-Huan,TANG Yu,LIU Wei-Sheng and TAN Min-Yu. Synthesis, Characterization and Luminescent Properties of Rare Earth Complexes with Podand Ligand Using Crown Ether as Skeleton[J]. Chinese Journal of Inorganic Chemistry, 2008, 24(8): 1356-1359 |
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| Authors: | LIU Dian-Yi YAN Xu-Huan TANG Yu LIU Wei-Sheng TAN Min-Yu |
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| Affiliation: | College of Chemistry and Chemical Engineering, State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000,College of Chemistry and Chemical Engineering, State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000,College of Chemistry and Chemical Engineering, State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000,College of Chemistry and Chemical Engineering, State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000 and College of Chemistry and Chemical Engineering, State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000 |
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| Abstract: | |
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| Keywords: | podand ligand crown ether rare earth complex luminescent property |
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