| Synthesis,Crystal Structure and Luminescent Property of Cadmium Complex Based on 2-（2-（1Hbenzo[d]imidazol-2-yl）benzyl）-1H-benzo[d]-imidazole |
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| 引用本文： | 苏文义,李国璧,潘荣楷,唐妃琼,钟玲,刘生桂.Synthesis,Crystal Structure and Luminescent Property of Cadmium Complex Based on 2-（2-（1Hbenzo[d]imidazol-2-yl）benzyl）-1H-benzo[d]-imidazole[J].结构化学,2014,33(6):108-113. |
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| 作者姓名： | 苏文义 李国璧 潘荣楷 唐妃琼 钟玲 刘生桂 |
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| 作者单位： | School of Chemistry Science and Technology,Zhanjiang Normal University, Zhanjiang, 524048, China |
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| 基金项目： | financially supported by the Natural Science Foundation of Guangdong Province(No.10152404801000017);Guangdong Province Undergraduate Training Programs for Innovation |
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| 摘 要： | The complex Cd(bbb)Cl2]·DMF·H2O, where bbb is 2-(2-(1H-benzod]imidazol-2-yl)benzyl)-1H-benzod]imidazole, was synthesized and characterized by X-ray single-crystal structure analyses. For the complex: C24H25Cl2CdN5O2, Mr = 598.77, crystal system, triclinic, space group P1, a = 9.9878(12), b = 10.0008(12), c = 13.2217(15) , α = 80.674(2), β = 72.158(2), γ = 86.776(2)°, V = 1240.5(3) 3, Z = 2, Dc = 1.598 g/cm3, λ = 0.71073, μ(MoKα) = 1.127 mm–1, F(000) = 600, S = 1.04, R = 0.0905 and wR = 0.3088 for 4805 observed reflections with I 2σ(I). It is a neutral complex. The distorted tetrahedral geometry of cadmium ion is coordinated by two nitrogen atoms of ligand and two chloride ions. The complex emits blue green luminescence with emission peaks at 480 nm in DMF solution.
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| 关 键 词： | 镉配合物 结构分析 咪唑 发光性能 合成 苄基 晶体 苯 |
Synthesis,Crystal Structure and Luminescent Property of Cadmium Complex Based on 2-(2-(1Hbenzo[d]imidazol-2-yl)benzyl)-1H-benzo[d]-imidazole |
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| SU Wen-Yi
,
LI Guo-Bi
,
PAN Rong-Kai
,
TANG Fei-Qiong
,
ZHONG Ling
,
LIU Sheng-Gui.Synthesis,Crystal Structure and Luminescent Property of Cadmium Complex Based on 2-(2-(1Hbenzo[d]imidazol-2-yl)benzyl)-1H-benzo[d]-imidazole[J].Chinese Journal of Structural Chemistry,2014,33(6):108-113. |
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| Authors: | SU Wen-Yi LI Guo-Bi PAN Rong-Kai TANG Fei-Qiong ZHONG Ling LIU Sheng-Gui |
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| Institution: | School of Chemistry Science and Technology,Zhanjiang Normal University, Zhanjiang, 524048, China |
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| Abstract: | benzimidazole,cadmium complex,crystal structure,luminescence |
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| Keywords: | benzimidazole cadmium complex crystal structure luminescence |
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