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| Structure and Nonlinear Optical Property of the Cluster Compound V_2S_6O_2Cu_6（3-MePy）_6 | |
| 引用本文： | 唐果东,张金方,宋瑛林,张弛,陆路德. Structure and Nonlinear Optical Property of the Cluster Compound V_2S_6O_2Cu_6（3-MePy）_6[J]. 结构化学, 2014, 33(6): 120-126 |
| 作者姓名： | 唐果东 张金方 宋瑛林 张弛 陆路德 |
| 作者单位： | [1]Jiangsu Key Laboratory for Chemistry. of Low-dimensional Materials, School of Chemistry and Chemical Engineering, Huaiyin Normal University, Huaian 223001, China; [2]Material Chemistry Laboratory, Nanjing University of Science and Technology, Nanjing 210094, China; [3]Research Center for Advanced Molecular Materials, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjing 212013, China; [4]School of Physical Science and Technology, Suzhou University, Suzhou 215006, China |
| 基金项目： | supported by Jiangsu Key Laboratory for Chemistry of Low-dimensional Materials Foundation(No.JSKC12110);the funds of high-grade scientific research project from Huaiyin Normal University;the National Science Foundation of Educational Commission of Jiangsu Province(No.12KJA150004);Huaian Key Laboratory for Photoelectric Conversion and Energy Storage Materials(No.HAP201205) |
| 摘 要： | A cluster compound V2S6O2Cu6(3-MePy)6(3-MePy = 3-methyl pyridine) has been synthesized by using skiving method and the crystal structure was characterized by X-raydiffraction: space group P1, Z = 1, a = 9.7278(4), b = 10.4180(5), c = 11.9230(6) , α = 108.240(3), β = 98.120(2), γ = 99.500(2)o, R = 0.052 and wR = 0.104. The NLO properties were studied by Z-scan technique with 8 ns pulsed laser at 532 nm. The cluster exhibits strong NLO absorptive ability(α2 = 1.7 × 10–10 m·W–1) and effective self-focusing performance(n2 = 1.27×10–18 m2·W–1) in a 1.58 × 10–4 mol·dm–3 DMF solution. |
| 关 键 词： | 晶体结构 3-甲基吡啶 Z-扫描技术 非线性特性 非线性光学 X光衍射 脉冲激光 吸收能力 |
Structure and Nonlinear Optical Property of the Cluster Compound V_2S_6O_2Cu_6(3-MePy)_6 |
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| TANG Guo-Dong , ZHANG Jin-Fang , SONG Ying-Lin , ZHANG Chi , LU Lu-De. Structure and Nonlinear Optical Property of the Cluster Compound V_2S_6O_2Cu_6(3-MePy)_6[J]. Chinese Journal of Structural Chemistry, 2014, 33(6): 120-126 | |
| Authors: | TANG Guo-Dong ZHANG Jin-Fang SONG Ying-Lin ZHANG Chi LU Lu-De |
| Affiliation: | 1. Jiangsu Key Laboratory for Chemistry of Low-dimensional Materials, School of Chemistry and Chemical Engineering, Huaiyin Normal University, Huaian 223001, China;Material Chemistry Laboratory, Nanjing University of Science and Technology, Nanjing 210094, China 2. Material Chemistry Laboratory, Nanjing University of Science and Technology, Nanjing 210094, China;Research Center for Advanced Molecular Materials, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjing 212013, China 3. School of Physical Science and Technology, Suzhou University, Suzhou 215006, China 4. Material Chemistry Laboratory, Nanjing University of Science and Technology, Nanjing 210094, China |
| Abstract: | crystal structure,nonlinear optics,vanadium cluster |
| Keywords: | crystal structure nonlinear optics vanadium cluster |
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