Crystal and molecular structure of N-(1-silatranylmethyl)benzimidazole |
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| Authors: | M. G. Voronkov É. A. Zelbst V. S. Fundamensky Yu. V. Katkevich Yu. I. Bolgova O. M. Trofimova N. F. Chernov |
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| Affiliation: | (1) A. E. Favorsky Irkutsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Russia;(2) Irkutsk State Pedagogical University, Russia |
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| Abstract: | The crystal and molecular structure of N-(1-silatranylmethyl)benzimidazole was established by X-ray diffraction. The coordination polyhedron of the silicon atom in this molecule is a trigonal bipyramid. The bond lengths and angles of the N-(1-silatranylmethyl)benzimidazole (SMBI) molecule are compared with the corresponding values for other derivatives of this heterocycle. The silatranylmethyl group, having a high electron-donor inductive effect, does not increase the total aromaticity of the SMBI molecule. |
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| Keywords: | N-(1-silatranylmethyl)benzimidazole silatranes X-ray structural analysis molecular structure |
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