| Study on Bicoordination Chiral Inducement Catalysis of （R）-4-Thiazolidinecarboxylic Acid |
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| 作者姓名： | HuiWANG WeiWeiPEI GuoBinSUN WeiPingYE |
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| 作者单位： | CollegeofChemistryandMolecularEngineering,PekingUniversity,Beijing100871 |
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| 摘 要： | The bicoordination chiral inducement catalysis of (R)-4-thiazolidinecarboxylic acid in the enantioselective borane reduction of prochiral ketones has been studied. The fact that the absolute configuration of the main product can be changed by simply using different operation methods was firstly verified. And the reason of bicoordination chiral inducement was discussed.
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| 关 键 词： | （R）-4-噻唑烷羧酸 配位手性诱导 催化合成 对应选择性 硼烷缩合物 前手性酮 |
Study on Bicoordination Chiral Inducement Catalysis of (R)-4-Thiazolidinecarboxylic Acid |
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| HuiWANG WeiWeiPEI GuoBinSUN WeiPingYE.Study on Bicoordination Chiral Inducement Catalysis of (R)-4-Thiazolidinecarboxylic Acid[J].Chinese Chemical Letters,2004,15(12):1419-1422. |
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| Authors: | Hui WANG Wei Wei PEI Guo Bin SUN Wei Ping YE College of Chemistry and Molecular Engineering Peking University Beijing |
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| Institution: | Hui WANG,Wei Wei PEI,Guo Bin SUN,Wei Ping YE College of Chemistry and Molecular Engineering,Peking University,Beijing 100871 |
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| Abstract: | The bicoordination chiral inducement catalysis of (R)-4-thiazolidinecarboxylic acid in
the enantioselective borane reduction of prochiral ketones has been studied. The fact that the
absolute configuration of the main product can be changed by simply using different operation
methods was firstly verified. And the reason of bicoordination chiral inducement was discussed. |
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| Keywords: | Bicoordination chiral inducement (R)-4-thiazolidinecarboxylic acid |
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