| Synthesis and Crystal Structure of a Mo-S Cluster Compound Coordinated by Isonicotinate |
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| 作者姓名： | 覃业燕 李兆基 康遥 张健 程建开 姚元根 |
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| 作者单位： | State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences，State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences，State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences，State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences，State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences，State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences，State Key Laboratory of Coordination Chemistry Nanjing University Nanjing 210093 China，Fuzhou Fujian 350002 China，Fuzhou Fujian 350002 China，Fuzhou Fujian 350002 China，Fuzhou Fujian 350002 China，Fuzhou Fujian 350002 China，Fuzhou Fujian 350002 China |
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| 基金项目： | 国家重点基础研究发展计划(973计划)
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the YIF
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国家自然科学基金
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Fujian Province, and the Major Special Foundation of Fujian Province |
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| 摘 要： | A cluster compound, Mo3S4(DTP)3(IN)(Py)·EtOH I (DTP = diethyl dithiophospha- te, IN = isonicotinate) has been rationally synthesized and characterized by single-crystal X-ray diffraction. The crystal belongs to the triclinic system, space group P1 with a = 13.6345(2), b = 13.7805(2), c = 14.5400(1) , α = 107.078(1), β = 113.380(1), γ = 96.310(1)o, C25H45Mo3- N2O9P3S10, Mr = 1218.96, V = 2315.75(5) 3, Z = 2, Dc = 1.748 g/cm3, μ = 1.399, F(000) = 1224, R = 0.0425 and wR = 0.1144 for 6335 observed reflections (I > 2σ(I)). 31P NMR spectrum has been measured with the resonance 110.050 and 108.783 (2:1).
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| 关 键 词： | 钼簇化合物 合成 晶体结构 二乙基二硫代磷酸盐 |
| 收稿时间： | 2006-12-30 |
| 修稿时间： | 2007-03-02 |
Synthesis and Crystal Structure of a Mo-S Cluster Compound Coordinated by Isonicotinate |
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| QIN Ye-Yan,LI Zhao-Ji,KANG Yao,ZHANG Jian,CHENG Jian-Kai,YAO Yuan-Gen.Synthesis and Crystal Structure of a Mo-S Cluster Compound Coordinated by Isonicotinate[J].Chinese Journal of Structural Chemistry,2007,26(9):1043-1046. |
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| Authors: | QIN Ye-Yan LI Zhao-Ji KANG Yao ZHANG Jian CHENG Jian-Kai YAO Yuan-Gen |
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| Abstract: | A cluster compound, Mo3S4(DTP)3(IN)(Py)·EtOH I (DTP = diethyl dithiophosphate, IN = isonicotinate) has been rationally synthesized and characterized by single-crystal X-ray diffraction. The crystal belongs to the triclinic system, space group Pi with a = 13.6345(2), b = 13.7805(2), c = 14.5400(1) (A), α = 107.078(1), β = 113.380(1), γ = 96.310(1)°, C25H45Mo3-N2O9P3S10, Mr = 1218.96, V= 2315.75(5) (A)3, Z = 2, Dc = 1.748 g/cm3, μ = 1.399, F(000) = 1224, R = 0.0425 and wR = 0.1144 for 6335 observed reflections (Ⅰ＞2σ(Ⅰ)). 31P NMR spectrum has been measured with the resonance 110.050 and 108.783 (2:1). |
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| Keywords: | molybdenum cluster synthesis crystal structure Isonicotinate Cluster Compound Crystal Structure NMR spectrum resonance space group crystal triclinic system synthesized and characterized diffraction isonicotinate dithiophosphate EtOH cluster compound |
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