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Characterization of Metallo-Supramolecular Systems by MALDI-TOF Mass Spectrometry
Authors:Ulrich S. Schubert  Christian Eschbaumer
Affiliation:(1) Lehrstuhl für Makromolekulare Stoffe, Technische Universität München, Lichtenbergstr. 4, 85747 Garching, Germany
Abstract:MALDI-TOF mass spectrometry was used for the characterization of metallo-supramolecular coordination arrays with molecular weights between 500 and 4000 g/mol. The stepwise loss of the counterions was used as an additional fingerprint for the investigated species. The isotope pattern yielded further information, especially in combination with simulations.
Keywords:MALDI-TOF-MS  supramolecular chemistry  metal coordination array  characterization in the solid state
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