Solid-state structures and superstructures of two charged donor-acceptor rotaxanes |
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Authors: | Yan-Li ZhaoAlexander K Shveyd J Fraser Stoddart |
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Institution: | Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA |
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Abstract: | Two 2]rotaxanes and a 2]pseudorotaxane containing 1,5-dioxynaphthalene recognition sites located in the middle of their dumbbell and thread components, respectively, and encircled by single cyclobis(paraquat-p-phenylene) rings have been synthesized under template control and their solid-state (super)structures have been solved. The investigations revealed that the stoppers on the dumbbell components, the solvents, and the counterions can affect the conformations adopted by the 2]rotaxanes and 2]pseudorotaxane in the solid state. |
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Keywords: | Conformation Crystal structure Hydrogen bonding Pseudorotaxane Rotaxane |
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