| A new chain-like heteropolytungstate formed by Keggin cluster units:Synthesis and structure of [H_2bpy]_3 [SiMnW_(11)O_(39)].1.25H_2O |
| |
| 作者姓名： | Jing Xin Meng Ying Ma Xin Xin Xu Yang Guang Li En Bo Wang~* Key Laboratory of Polyoxometalate Science of Ministry of Education |
| |
| 作者单位： | Jing Xin Meng Ying Ma Xin Xin Xu Yang Guang Li En Bo Wang~* Key Laboratory of Polyoxometalate Science of Ministry of Education Department of Chemistry，Northeast Normal University Ren Min Street No.5268，Changchun，Jilin，130024，PR China |
| |
| 摘 要： | A new heteropolytungstate,H_2bpy]_3SiMnW_(11)O_(39)].1.25H_2O(1),has been prepared under mild hydrothermal conditions and structurally characterized by single crystal X-ray diffraction.It is the first characterized compound containing 1D zigzag chain of transition metal substituted Keggin heteropolytungstate,which is connected through a common oxygen atom.The elemental analysis and IR of it are also described.
|
| 收稿时间： | 15 May 2006 |
A new chain-like heteropolytungstate formed by Keggin cluster units: Synthesis and structure of [H2bpy]3[SiMnW11O39]·1.25H2O |
| |
| Jing Xin Meng Ying Ma Xin Xin Xu Yang Guang Li En Bo Wang* Key Laboratory of Polyoxometalate Science of Ministry of Education.A new chain-like heteropolytungstate formed by Keggin cluster units:Synthesis and structure of [H_2bpy]_3 [SiMnW_(11)O_(39)].1.25H_2O[J].Chinese Chemical Letters,2007,18(1):81-84. |
| |
| Authors: | Jing Xin Meng Ying Ma Xin Xin Xu Yang Guang Li En Bo Wang |
| |
| Institution: | Key Laboratory of Polyoxometalate Science of Ministry of Education Department of Chemistry, Northeast Normal University Ren Min Street No.5268, Changchun, Jilin, 130024, PR China |
| |
| Abstract: | A new heteropolytungstate,H_2bpy]_3SiMnW_(11)O_(39)].1.25H_2O(1),has been prepared under mild hydrothermal conditions and structurally characterized by single crystal X-ray diffraction.It is the first characterized compound containing 1D zigzag chain of transition metal substituted Keggin heteropolytungstate,which is connected through a common oxygen atom.The elemental analysis and IR of it are also described. |
| |
| Keywords: | Heteropolytungstate Keggin clusters Zigzag chain |
| 本文献已被 CNKI 万方数据 ScienceDirect 等数据库收录！ |
