Reaction of vinyl radicals with propylene in the gas phase |
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| Authors: | J Niedzielski J Gawowski and W Makulski |
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| Institution: | (1) Department of Chemistry, Warsaw University, Zwirki i Wigury 101, 02-089 Warsaw, Poland |
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| Abstract: | The reaction of vinyl radicals with propylene and propyl radicals was investigated in the gas phase. The radicals were produced by mercury sensitized decomposition of molecular hydrogen followed by addition of hydrogen atoms to propylene and acetylene. Vinyl radical adds to propylene effectively while hydrogen atom abstraction does not occur.
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