Direct correlation function for complex square barrier-square well potentials in the first-order mean spherical approximation |
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Authors: | Hlushak S P Trokhymchuk A D Soko?owski S |
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Institution: | Institute for Condensed Matter Physics, National Academy of Sciences of Ukraine, Lviv 79011, Ukraine. |
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Abstract: | The direct correlation function of the complex discrete potential model fluids is obtained as a linear combination of the first-order mean spherical approximation (FMSA) solution for the simple square well model that has been reported recently Hlushak et al., J. Chem. Phys. 130, 234511 (2009)]. The theory is employed to evaluate the structure and thermodynamics of complex fluids based on the square well-barrier and square well-barrier-well discrete potential models. Obtained results are compared with theoretical predictions of the hybrid mean spherical approximation, already reported in the literature Guillen-Escamilla et al., J. Phys.: Condens. Matter 19, 086224 (2007)], and with computer simulation data of this study. The compressibility route to thermodynamics is then used to check whether the FMSA theory is able to predict multiple fluid-fluid transitions for the square barrier-well model fluids. |
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