Thermodynamic Properties and Selectivity of Mesomorphic p-n-Alkoxycinnamoyloxy-p"-Cyanoazobenzenes As Stationary Phases in Gas Chromatography |
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Authors: | S. V. Blokhina G. G. Maidachenko A. V. Sharapova M. V. Ol'khovich A. N. Trostin |
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Affiliation: | (1) Institute of Chemistry of Solutions, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia |
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Abstract: | The retention of n-alcohols, xylene and naphthol isomers, and polycyclic aromatic hydrocarbons was studied by gas chromatography using stationary phases based on mesomorphic p-n-alkoxycinnamoyloxy-p"-cyanoazobenzenes. Thermodynamic interpretation of the structural selectivity of the smectic and nematic phases of mesogens was proposed. |
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