| 沸石的包结作用提高分子内萘蒽的交叉光加成 |
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| 引用本文： | 佟振合,苏宁,吴骊珠,苑振宇.沸石的包结作用提高分子内萘蒽的交叉光加成[J].影像科学与光化学,1998,16(2):111-116. |
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| 作者姓名： | 佟振合 苏宁 吴骊珠 苑振宇 |
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| 作者单位： | 中国科学院感光化学研究所, 北京100101 |
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| 基金项目： | 国家自然科学基金资助项目(批准号:29392205),中科院基础局项目(KJ951-A-1-503). |
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| 摘 要： | 萘与萘、蒽与蒽的光二聚反应已经被广泛研究,但萘与蒽的交叉光二聚反应报道不多。我们合成了两末端分别以萘和蒽标记的聚醚化合物,利用NaY沸石的孔腔作为纳米反应器,将此化合物置于孔腔中,通过光反应得到分子内的萘和蒽交叉二聚体。
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| 关 键 词： | 沸石 萘蒽交叉光加成 双发色团分子 |
| 收稿时间： | 1997-12-23 |
ENHANCEMENT OF PHOTOINDUCED INTRAMOLECULAR CROSS DIMERIZATION BETWEEN NAPHTHALENE AND ANTHRACENE MOIETIES VIA INCLUSION WITHIN ZEOLITE |
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| TONG Zhenhe.ENHANCEMENT OF PHOTOINDUCED INTRAMOLECULAR CROSS DIMERIZATION BETWEEN NAPHTHALENE AND ANTHRACENE MOIETIES VIA INCLUSION WITHIN ZEOLITE[J].Imaging Science and Photochemistry,1998,16(2):111-116. |
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| Authors: | TONG Zhenhe |
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| Institution: | Institute of Photographic Chemistry, The Chinese Academy of Sciences, Beijing 100101, P. R. China |
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| Abstract: | Although the photodimerizat ion of anthracene1] and that of naphthalene2,3] have beenext ensively studied,until recently relatively little has been reported on the cross-phot odimer-ization between an ant hracene and a naphthalene moiety4]. |
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| Keywords: | zeolite cross-photodimerization between naphthalene and anthrancene bichromophoric molecule |
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