Synthesis and Spectroscopic Characterization of Transition Metal Complexes of Maleionitriledithiolate and 5-Nitro-Phenanthroline |
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Authors: | PENG Zheng-he PAN Qing-cai REN Xiao-ming FANG Chen-jie QIN Zi-bin |
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Institution: | Department of Chemistry, Wuhan University, Wuhan 430072;State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 200093 |
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Abstract: | The dithiolenes and diimines and their metal complexes are an important research field in the organic and coordination chemistry1-3]. Transition metal complexes of a dithiolene and a diimine have excellent electronic functions due to the intramolecular charge transfer from a ligand to other ligand (LL'CT)3], in which are interested authors4,5]. Recently we have been studied in detail the synthesis and properties of the title complexes M(mnt)(5-NO2-phen), M=MnⅡ, FeⅡ, CoⅡ, NiⅡ, CuⅡ, ZnⅡ. The structure and properties of the M(mnt)(5-NO2-phen) were characterized by the elemental analysis, TDA-TG, MASS, IR, UV-Vis, fluorescence and EPR spectra,molar conductivity and magnetic susceptibility. In the present abstract we report only the synthesis and spectroscopic characterization of these complexes. |
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