Reaction of 1,2-bis(cyclopentadienyl)tetramethyl digermane with Ru3(CO)12 |
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Authors: | Yongqiang Zhang Baiquan Wang Shansheng Xu Xiuzhong Zhou |
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Institution: | Department of Chemistry, Nankai University, Tianjin 300071 |
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Abstract: | We have recently reported a novel rearrangement reaction involving an intramolecular metathesis between M-M and Fe-Fe bonds in the dinuclear iron complexes (Me2MMMe2)η5-C5R4)Fe(CO)]2(μ-CO)2 (M=Si, Ge; R=H, Me):1-5].In order to extend the applied range of the rearrangement reaction we tried to synthesize the digermyl briged diruthenium analogues. The results showed a great difference between them. |
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