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Reaction of 1,2-bis(cyclopentadienyl)tetramethyl digermane with Ru3(CO)12
Authors:Yongqiang Zhang  Baiquan Wang  Shansheng Xu  Xiuzhong Zhou
Institution:Department of Chemistry, Nankai University, Tianjin 300071
Abstract:We have recently reported a novel rearrangement reaction involving an intramolecular metathesis between M-M and Fe-Fe bonds in the dinuclear iron complexes (Me2MMMe25-C5R4)Fe(CO)]2(μ-CO)2 (M=Si, Ge; R=H, Me):1-5].In order to extend the applied range of the rearrangement reaction we tried to synthesize the digermyl briged diruthenium analogues. The results showed a great difference between them.
Keywords:
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