Synthesis and Fluorescence of a New Active Material for Electrochemiluminescent Sensor:Ru(phen)2[phen-NHCO(CH2)4Br](PF6)2 |
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| Authors: | SHU Huo-Ming WANG Peng TIAN Fa-Ming ZHU Guo-Yi |
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| Affiliation: | 1. Department of Chemistry, Hainan Normal University, Haikou 571158, P. R. China;2. Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China |
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| Abstract: | Recently, much attention has been paid to Ru(II) complexes because of their excellent properties of photochemistry, phtophysis. Bis(2,2'-bipyridine)[4-methyl-4'-(6-bromohexyl)-2,2'-bipyridine] ruthenium(II) perchlorate has been used as an active material for electrochemiluminescent (ECL) sensor for selective detection of oxalic acid.It is known that ECL efficiency of Ru(phen)32+ is much higher than that of Ru(bpy)32+. In order to make out more efficient ECL sensor, we have designed and synthesized a new Ru(II) complex, Ru(phen)2[phen-NHCO(CH2)4Br](PF6)2. |
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