Soluble, reactive and stable - unique aluminosilicate ligands and a heterobimetallic derivative [LAl(SLi)(micro-O)Si(OLi.2thf)(OtBu)2]2 |
| |
| Authors: | Jancik Vojtech Rascón-Cruz Fernando Cea-Olivares Raymundo Toscano Rubén A |
| |
| Institution: | Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, 04510, México DF, México. |
| |
| Abstract: | The heterobimetallic aluminosilicate LAl(SLi)(micro-O)Si(OLi.2thf)(O(t)Bu)(2)](2) was prepared from the LAl(SH)(micro-O)Si(OH)(O(t)Bu)(2) (L = HC{C(Me)N(Ar)}(2)](-), Ar = 2,6-di-(i)Pr(2)C(6)H(3)) ligand, which can also be hydrolyzed to LAl(OH.thf)(micro-O)Si(OH)(O(t)Bu)(2)- leading to the first aluminosilicate-dihydroxide soluble in organic solvents. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
