133Cs and deuteron NMR study of the superionic transition in CsDSO4 |
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Institution: | 1. Nuclear Research Center Negev, PO Box 9001, Beer Sheva 84901, Israel;2. Israel Atomic Energy Commission (IAEC) Israel;3. School of Chemistry, Tel Aviv University, Ramat Aviv 6997801, Tel Aviv, Israel |
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Abstract: | The temperature dependence of the 133Cs and deuteron NMR spectra of a CsDSO4 single crystal has been investigated between 20°C and 170°C. In the room temperature phase II' there are two physically non-equivalent Cs+ and deuteron sites per unit cell. On heating from room temperature to 110°C the doublet structure of the 133Cs and deuteron lines collapses due to random Cs and deuteron exchange between the two non-equivalent sites. At the transition to the superionic phase III there is a further drastic decrease in the deuteron and a somewhat smaller decrease in the 133Cs quadrupole coupling. The fact that the quadrupole coupling of these two nuclei remains non-zero in the superionic phase demonstrates that the Cs+ and deuteron translational diffusion involves well defined lattice sites and directions and is not completely “random” or “liquid”-like. |
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