Rate constant of non-adiabatic processes on a metal surface |
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| Affiliation: | 1. Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai, 400076, India;2. School of Chemical Sciences, Indian Association for the Cultivation of Science, Jadavpur, Kolkata, 700032, India;3. Department of Chemistry, Jagannath Kishore College, Post & District-Purulia, Purulia, 723101, India |
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| Abstract: | The rate constant of non-adiabatic activated processes is expressed as k = κkTST, where kTST is the transition-state-theory rate constant. In the present paper the transmission coefficient, κ, is derived for the rate process limited by weak coupling of the initial electronic diabatic state with a continuum of the final diabatic states. |
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