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Chemical thermodynamics and theoretical models
Affiliation:1. School of Chemistry Engineering, Linyi University, Linyi 276000, China;2. Tianjin Key Laboratory of Marine Resources and Chemistry, Tianjin University of Science and Technology, Tianjin 300457, China;1. Centro de Química Estutural, Faculdade de Ciências da Universidade de Lisboa, Ed. C8, Campo Grande, 1649-016, Lisboa, Portugal;2. University of Tartu, Institute of Chemistry, Ravila 14a, 50411, Tartu, Estonia;3. Finnish Environment Institute SYKE, Laboratory Centre, Mustialankatu 3, 00790, Helsinki, Finland;4. Laboratoire National de Metrologie et D''Essais, 1 Rue Gaston Boissier, 75015, Paris, France;5. DFM A/S, Kogle Allé 5, 2970, Hørsholm, Denmark;6. Physikalisch-Technische Bundesanstalt, Bundesallee 100, 38116, Braunschweig, Germany;1. State Key Laboratory of Rice Biology, Institute of Biotechnology, Zhejiang University, Hangzhou 310012, P.R.China;2. State Key Laboratory for Biology of Plant Diseases and Insect Pests, Institute of Plant Protection, Chinese Academy of Agricultural Sciences, Beijing 100193, P.R.China
Abstract:This paper presents a brief discussion of the relationship between classical thermodynamics and theoretical models of chemical systems. Applications of thermodynamics to real chemical systems and to related theoretical models concerning “complexes in nonelectrolyte solutions” and “substituent and solvent effects in organic chemistry” are described, with particular emphasis on research that my colleagues and I have done in these areas. This paper concludes with a brief autobiographical section on “people and places”.
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