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Resonant Raman scattering from molecules adsorbed on non-metallic surfaces: An exact solution
Institution:1. Department of Sensory and Motor System Medicine, Graduate School of Medicine, The University of Tokyo, Hongo 7-3-1, Bunkyo-ku, Tokyo 113-8655, Japan;2. Towada City Hospital, Nishi 12-14-8, Towada-shi, Aomori 034-0093, Japan;3. Towadako Clinic, Yasumiya 16-195, Towadakohan, Towada-shi, Aomori 018-5501, Japan;4. Department of Oral and Maxillofacial Surgery, Nihon University School of Dentistry, Kanda-Surugadai 1-8-13, Chiyoda-ku, Tokyo 101-8310, Japan;1. Biological Physics Laboratory, Physics Institute, San Luis Potosí, Mexico;2. Department of Physiology and Biophysics, School of Medicine, Universidad Autónoma de San Luis Potosí, San Luis Potosí, Mexico;1. School of Energy and Power Engineering, Beihang University, Beijing, 100191, China;2. Department of Mechanical Engineering, Imperial College London, London, SW72AZ, UK;3. Department of Mechanical Engineering, University of Connecticut, Storrs, CT, 06269, USA
Abstract:A model of resonant Raman scattering of molecules weakly adsorbed on non-metallic surfaces is solved exactly. The model embodies the non-radiative electromagnetic interaction between molecule dipole transition and solid excitation, when the dominant screening effect is due to interband transitions or molecular excitons.The role of interband transitions in the resonant Raman response is also discussed by selected numerical examples in polaronic and non-polaronic regimes.
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