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Spectroscopic investigation of CaFeSn(PO4)3
Institution:1. CAS Key Laboratory of Crust-Mantle Materials and Environments, School of Earth and Space Sciences, University of Science and Technology of China, Hefei, Anhui, 230026, China;2. Dipartimento di Ingegneria Dell''Ambiente, Università Della Calabria Rende, 87036, Rende (CS), Italy;3. Institute of Geology, University of Azad Jammu and Kashmir, Muzaffarabad, 13100, Pakistan;4. College of New Energy and Environment, Jilin University, Changchun, Jilin, 130021, China;1. PG & Research Department of Physics, AVVM Sri Pushpam College (Autonomous) [Affiliated to Bharathidasan University, Tiruchirappalli], Poondi, Thanjavur, 613 503, Tamil Nadu, India;2. Department of Nanotechnology, Noorul Islam centre for Higher Education, Thuckalay, Kumaracoil, Kanyakumari, 629 128, Tamil Nadu, India;3. PG & Research Department of Botany, AVVM Sri Pushpam College (Autonomous) [Affiliated to Bharathidasan University, Tiruchirappalli], Poondi, Thanjavur, 613 503, Tamil Nadu, India;4. PG & Research Department of Chemistry, AVVM Sri Pushpam College (Autonomous) [Affiliated to Bharathidasan University, Tiruchirappalli], Poondi, Thanjavur, 613 503, Tamil Nadu, India;5. PG& Research Department of Physics, Kongunadu College of Engineering and Technology [Affiliated to Anna University, Chennai], Thottiyam, Tiruchirappalli, 621 215, Tamil Nadu, India;1. Departamento de Química, Área de Catálisis, Universidad Autónoma Metropolitana – Iztapalapa, Av. San Rafael Atlixco No. 189, C.P. 09340 Ciudad de México, Mexico;2. Instituto Nacional de Investigaciones Nucleares, Carretera México-Toluca S/N La Marquesa, Ocoyoacac, C.P. 52750 Estado de México, Mexico;3. Departamento de Biociencias e Ingeniería, Centro Interdisciplinario de Investigaciones y Estudios sobre Medio Ambiente y Desarrollo (CIIEMAD), Instituto Politécnico Nacional, C.P. 07340 Ciudad de México, Mexico;4. Facultad de Ingeniería Química, Benemérita Universidad Autónoma de Puebla, Ciudad Universitaria, colonia Jardines de San Manuel, C.P. 72570 Puebla, Puebla, Mexico;5. Departamento de Química, Universidad de Guanajuato, Cerro de la Venada S/N, Pueblito de Rocha, C.P. 36040 Guanajuato, Gto, Mexico
Abstract:Infrared and Raman spectra of CaFeSn(PO4)3 have been recorded and discussed with the aid of a site-symmetry analysis. The Mössbauer (57119Fe and 119Sn) spectra of this compound as well as the Sn-spectra of KSn2(PO4)3 and TlSn2(PO4)3 were also reported. The obtained spectroscopic information allows a deeper insight into the structural and electronic properties of this type of solids.
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