Control over <Emphasis Type="Italic">m</Emphasis>-nitrotoluene concentration in products of heterogeneous mononitration of toluene |
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Authors: | A V Artemov I V Tselinskii S A Kukushkin E V Filatova V V Ashikhin |
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Institution: | (1) St. Petersburg State Institute of Technology (Technical University), St. Petersburg, Russia |
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Abstract: | Heterogeneous mononitration of toluene with sulfuric-nitric acid mixtures, occurring in the charged interfacial monolayer with high para selectivity, was studied. Ways to suppress the meta substitution in the toluene mononitration stage by controlling the nitrating mixture composition, process parameters, and catalytic additives were found. |
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