| 季铵盐型离子液体中全氟烷基磺酰亚胺盐催化的芳烃硝化反应 |
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| 引用本文： | 王烁今,孙智英,聂进,. 季铵盐型离子液体中全氟烷基磺酰亚胺盐催化的芳烃硝化反应[J]. 中国化学, 2008, 26(12): 2256-2260. DOI: 10.1002/cjoc.200890400 |
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| 作者姓名： | 王烁今 孙智英 聂进 |
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| 作者单位： | 1 华中科技大学化学与化工学院，武汉，430074 ;2 材料化学与服役失效湖北省重点实验室，武汉，430074 ; |
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| 摘 要： | 全氟烷基磺酰亚胺盐与季铵型离子液体（Cu(N(C4F9SO2)2)2/[N4446][NTf2] 或 In(NTf2)3/[N4446][NTf2]）组成的新催化体系，可以很好的催化芳香族化合物的硝化反应。以氯苯的硝化为例，用硝酸和醋酸酐混合物为硝化试剂，在2mol%的Cu(N(C4F9SO2)2)2或In(NTf2)3催化剂催化下，室温下反应10分钟，氯苯的转化率就可分别达到87.6% 和 90.6%，反应产物的邻/对位比为4.3和4.8。并且这种催化剂与离子液体组成的催化体系很容易被回收，并可以连续使用5次以上。
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| 关 键 词： | 硝化 离子液体 全氟烷基磺酰亚胺盐 催化 |
| 收稿时间： | 2008-06-01 |
| 修稿时间： | 2008-07-06 |
Nitration of Substituted Benzenes Catalyzed by Metal Bis[(perfluoroalkyl)sulfonyl]imides in Quaternary Ammonium Ionic Liquids |
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| Shuo‐Jin WANG,Zhi‐Ying SUN,Jin NIE. Nitration of Substituted Benzenes Catalyzed by Metal Bis[(perfluoroalkyl)sulfonyl]imides in Quaternary Ammonium Ionic Liquids[J]. Chinese Journal of Chemistry, 2008, 26(12): 2256-2260. DOI: 10.1002/cjoc.200890400 |
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| Authors: | Shuo‐Jin WANG Zhi‐Ying SUN Jin NIE |
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| Affiliation: | Hubei Key Laboratory of Materials Chemistry & Service Failure, Department of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, Hubei 430074, China |
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| Abstract: | The nitrations of substituted benzenes proceeded rapidly and cleanly with very good yields in Cu(N(C4F9SO2)2)2/ [N4446][Tf2N] or In(NTf2)3/[N4446][Tf2N] catalyst system, in which HNO3/Ac2O was used as the nitrating agent. For the nitration of chlorobenzene when 2 mol% catalyst was used at room temperature for 10 min, 87.6% and 90.6% of conversion of chlorobenzene were achieved, respectively and the para/ortho ratios of products were about 4.3–4.8. The catalyst systems with ionic liquid could be recovered easily and reused more than 5 times. |
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| Keywords: | nitration ionic liquid metal bis[(perfluoroalkyl)sulfonyl]imide catalysis |
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