Structure analysis of [Be(NCS)2(C5H5N)2] |
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| Authors: | H Böhland W Hanay M Noltemeyer A Meller H G Schmidt |
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| Institution: | Department of Chemistry, P?dagogische Hochschule Erfurt, Postfach 307, D-99006 Erfurt, Germany, DE
Institute of Inorganic Chemistry, Georg-August-University G?ttingen, Tammannstrasse 4, D-37077 G?ttingen, Germany, DE
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| Abstract: | Be(NCS)2(C5H5N)2] was prepared and characterized by chemical analysis, FT-IR-analysis, and single crystal X-ray structure analysis. The crystals are orthorhombic with a = 829.30(10) pm, b = 1292.1(2) pm, c = 1313.40(10) pm, space group Pnma. Z = 4. The structure is built up from tetrahedra. Hydrogen bonding between the S-atom of one Be-N-bonded thiocyanate and 1.3-H-atoms of pyridine ligands yield a three dimensional network consisting of folded sheets. |
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