In Situ FT-IR Studies of the Zirconium (IV) Acetylacetonate Catalyzed Urethane Reaction of Butanediols |
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Authors: | Shun Ping Wang Xiao Deng Yang Qing Quan Bai |
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Institution: | 1. Shandong Provincial Key Laboratory of Fine Chemicals , Shandong Polytechnic University , Jinan , China;2. Shandong Leahou Light Industrial of New Material Co., Ltd. , China;3. Shandong Provincial Key Laboratory of Fine Chemicals , Shandong Polytechnic University , Jinan , China;4. Shandong Leahou Light Industrial of New Material Co., Ltd. , China |
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Abstract: | A comparative kinetic study of the urethane reactions of phenyl isocyanate and 1,2-, 1,3-, and 1,4-butanediol was carried out in dichloromethane solution with zirconium (IV) acetylacetonate as catalyst. In situ FT-IR was used to follow the kinetics of the reactions at a constant temperature of 15°–30°C. The rate constants for the reaction of the primary hydroxyl group and the secondary hydroxyl group were calculated as k prim and k sec, respectively. Analysis of the second-order rate constants of these systems indicated that k prim follows 1,2-butanediol >1,3-butanediol >1,4-butanediol. The ratio of k prim/k sec in 1,2-butanediol was the highest and the order followed was the same as with the reaction rate. Activation energies and Eyring parameters were also determined for the urethane reaction of butanediols. |
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Keywords: | Butanediol Catalyst In situ FT-IR Polyurethane |
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