Application of the Prigogine-Flory-Patterson theory part III. Mixtures of a bicyclic compound,benzene, cyclohexane,n-hexane with a cycloalkane,cyclohexene, a cycloalkadiene and benzene |
| |
Authors: | T. M. Letcher R. C. Baxter |
| |
Affiliation: | (1) Department of Chemistry, Rhodes University, 6140 Grahamstown, South Africa |
| |
Abstract: | The Prigogine-Flory-Patterson theory of liquid mixtures has been qpplied to the HmE and VmE for binary mixtures of a bicyclic compound, benzene, cyclohexane and n-hexane with a cycloalkane, cyclohexene, a cycloalkadiene and benzene. Furthermore the Prigogine-Flory theory has been used to predict activity coefficients at infinite dilution from the experimentally determined HmE at 25°C for the mixtures cyclohexane, cyclohexene, 1,3-cyclohexadiene, 1,4-cyclohexadiene and benzene with a bicyclic compound. The predictions are compared to experimental results. |
| |
Keywords: | Excess molar enthalpies excess molar volumes decalin bicyclohexyl tetralin cyclohexylbenzene cyclopentane cyclohexane cyclohexene 1,3-cyclohexadiene 1,4-cyclohexadiene cycloheptane cyclooctane benzene n-hexane Prigogine-Flory-Patterson theory Prigogine-Flory theory activity coefficients at infinite dilution |
本文献已被 SpringerLink 等数据库收录! |
|