Preparation and diels-alder reactions of a pyranoid vinyl glycal:model studies for anthraquinone aglycone and carbohydrate syntheses |
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Institution: | 1. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi''an, Shaanxi 710069, PR China;2. College of Science, Xi''an University of Architecture and Technology, Xi''an, Shaanxi 710055, PR China |
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Abstract: | The preparation of a conjugated pyranoid vinyl glycal is reported, along with several of its thermal 4+2] cycloaddition reactions with a variety of dienophiles. Applications to the anthraquinone antitumor agents are discussed. |
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