ChemInform Abstract: Trends in Gas-Phase Fluoride Ion Affinities of Main-Group Oxyfluorides and Fluoride Sulfides. Generation and Characterization of the Fluoride Adducts of FAsO,FPO, FPO2, F2SiO,F4SO,FBO, F2SiS,FPS, FAsS,F2S2, and S2O by Ion Cyclotron Resonance Addition-Elimination Reactions. |
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| Authors: | J. W. LARSON T. B. MCMAHON |
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| Abstract: | Novel oxyfluoride and fluoride sulfide anions are generated by the isoelectronic replacement of F in a main-group polyfluoride by O- or S- via the reaction of either tBuO- or RS- (R: H, Me) with the polyfluorides. |
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| Keywords: | theory, structure fluorine, F |
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