Solvent effect on the rate of homogeneous electron exchange of the Eu(III)-Eu(II) system in water-DMF mixtures |
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| Authors: | A Czerwiński |
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| Institution: | (1) Chemistry Department, Warsaw University, 02-089 Warsaw, Poland |
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| Abstract: | The kinetics of homogeneous electron exchange Eu3+/Eu2+ has been investigated in 1M HClO4, water+dimethylformamide (DMF) mixed solvent by using labeled europium. Non-monotonic variations of the electron exchange rate constants as a function of the solvent composition was observed. |
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