Synthesis,Characterization and Investigation of Electrochemical and Spectroelectrochemical Properties of Peripherally Tetra Diethoxypropan Substituted Phthalocyanines |
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| Authors: | Duygu Akyüz Hakkı Türker Akçay Rıza Bayrak |
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| Institution: | 1. Department of Chemistry, Faculty of Science, Gebze Technical University, Kocaeli, Turkey;2. Department of Chemistry, Faculty of Arts and Sciences, Recep Tayyip Erdoğan University, Rize, Turkey;3. Department of Medical Laboratory Techniques, Vocational School of Health Services, Sinop University, Sinop, Turkey |
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| Abstract: | In this study novel peripherally tetra 1,3-diethoxy-2-propanol substituted Co(II), Cu(II), Mg(II), Ni(II) Zn(II) phthalocyanine derivatives were prepared. The characterization of the novel compounds was made by FT-IR, 1H-NMR, UV-vis and MALDI-TOF mass. Electrochemical, in-situ spectroelectrochemical and electrocolorimetric measurements have been carried out with the aim to determine the redox properties, to illuminate reaction mechanism and the effect of substituent and metal center. Moreover, the color properties and aggregation tendency of compounds were also investigated. |
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| Keywords: | phthalocyanine 1 3-diethoxy-2-propanol electrochemistry spectroelectrochemistry electrocolorimetry |
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