A thermally stable and sterically unprotected terminal electrophilic phosphinidene complex of cobalt and its conversion to an eta(1)-phosphirene |
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| Authors: | Sánchez-Nieves Javier Sterenberg Brian T Udachin Konstantin A Carty Arthur J |
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| Institution: | Steacie Institute for Molecular Sciences, National Research Council of Canada, 100 Sussex Drive, Ottawa, Ontario, Canada K1A 0R6. |
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| Abstract: | The terminal chloroaminophosphido complex Co(CO)3(PPh3){P(Cl)NiPr2}] is formed via reaction of KCo(CO)4] with iPr2NPCl2 in the presence of triphenylphosphine. Chloride abstraction by aluminum trichloride leads to the first terminal phosphinidene complex of cobalt, Co(CO)3(PPh3)(PNiPr2)]AlCl4]. The electrophilicity of the phosphinidene was demonstrated by its reaction with diphenylacetylene to form the phosphirene complex Co(CO)3(PPh3){P(NiPr2)C(Ph)C(Ph)}]AlCl4]. |
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