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交流阻抗法研究BTA和MBT对铜的缓蚀行为
引用本文:童汝亭,周国定.交流阻抗法研究BTA和MBT对铜的缓蚀行为[J].化学研究与应用,1996,8(3):329-333.
作者姓名:童汝亭  周国定
作者单位:河北师范大学化学系,上海电力学院动力系,北京大学化学系
摘    要:采用交流阻抗法研究了在3%NaCl溶液中BTA和MBT对铜电极的缓蚀行为。结果表明:二者均有缓蚀作用;浸泡15分钟时,在浓度低于20ppm时,BTA优于MBT;而在40ppm时MBT优于BTA。二者有显著的协同效应,最佳化率是20ppmBTA+20ppmMBT。

关 键 词:交流阻抗    缓蚀剂  BTA  MBT

IMPEDENCE INVESTIGATIONS ON CORROSION INHIBITION OF COPPER BY BENZOTRIAZOLE AND 2 MERCAPTOBENZOTHIAZOLE IN A 3% NaCl SOLUTION
Tong,Ruting Ma,Zhichuan.IMPEDENCE INVESTIGATIONS ON CORROSION INHIBITION OF COPPER BY BENZOTRIAZOLE AND 2 MERCAPTOBENZOTHIAZOLE IN A 3% NaCl SOLUTION[J].Chemical Research and Application,1996,8(3):329-333.
Authors:Tong  Ruting Ma  Zhichuan
Abstract:Impedance measurement of copper electrodes in 3% NaCl solutions (pH6) in which benzotriazole (BTA) and/or 2 mercaptobenzothiazole (MBT) were added.Corrision inhibition of copper after 15min,immersion is ameliorrated by BTA as compared with that by MBT in concentraions below 20ppm,and is more effective with MBT at concentration above 40ppm.A combination of BTA and MBT gives a synergistic effect,and the optimum radio with 40ppm inhibition is 20ppmBTA+20ppmMBT.
Keywords:Impedance    measurements  Corrision    inhibition    of    copper    benzotriazole    2  mercaptobenzothiazole  
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