| Dioxygen Affinities and Catalytic Oxidation Performance of Cobalt (II)Complexes with N-Aryl Hydroxamic Acid |
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| 作者姓名： | Chun Chun ZHANG Wei ZENG Jian Zhang LI Sheng Ying QIN* |
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| 作者单位： | Chun Chun ZHANG，Wei ZENG，Jian Zhang LI，Sheng Ying QIN* Department of Chemistry，Sichuan University，Chengdu 610064 |
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| 摘 要： | It is well known that the study on biomimetic oxygen carriers not only has important theoretic significance to discover the mechanism of reversible bonding, activating oxygen as well as the oxidation reaction in organism, but also has potential application in separating oxygen from air and realizing the high efficiency and selectivity of catalytic oxidation reaction under a mild condition1. Metal- porphyrin and metal- phthalol- gaunine have been extensively used as biomimetic oxygen carriers u…
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Dioxygen Affinities and Catalytic Oxidation Performance of Cobalt (II)Complexes with N-Aryl Hydroxamic Acid |
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| Chun Chun ZHANG,Wei ZENG,Jian Zhang LI,Sheng Ying QIN*.Dioxygen Affinities and Catalytic Oxidation Performance of Cobalt (II)Complexes with N-Aryl Hydroxamic Acid[J].Chinese Chemical Letters,2003(6). |
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| Authors: | Chun Chun ZHANG Wei ZENG Jian Zhang LI Sheng Ying QIN |
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| Institution: | Chun Chun ZHANG,Wei ZENG,Jian Zhang LI,Sheng Ying QIN* Department of Chemistry,Sichuan University,Chengdu 610064 |
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| Abstract: | The oxygenation of cobalt (II) hydroxamates (CoL2) and its catalytic performance in oxidation of p-xylene to p-toluic acid (PTA) were examined. The effects of X and Y bonded to hydroxamate group on dioxygen affinities and catalytic oxidation performance were also investigated. |
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| Keywords: | Cobalt (II) hydroxamates dioxygen affinities catalytic oxidation p-xylene |
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