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Crystallization of polymers in variable external conditions IV. Isothermal crystallization in the presence of variable tensile stress or hydrostatic pressure
Authors:A Ziabicki
Institution:(1) Polish Academy of Sciences Institute of Fundamental Technological Research, 21 Swietokrzyska St., Warsaw, Poland, PL
Abstract:General equations of crystallization in variable conditions have been applied to isothermal crystallization affected by variable tensile stress or hydrostatic pressure. In a system under stress, the crystallization rate involves relaxational and athermal effects, and is controlled by the normal stress difference and the stress rate. Similarily, pressure effects include the hydrostatic pressure and its rate of change. Received: 1 December 1998 Accepted in revised form: 23 March 1999
Keywords:Nucleation theory  Thermal and athermal nucleation  Crystallization  Stress-induced crystallization  Pressure-induced crystallization
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