Thermal decomposition of sulphate complexes of uranium(IV) hydrates |
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| Authors: | J. Martin Gil F. Martinez Villa F. J. Martin Gil |
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| Affiliation: | 1. Department of Inorganic Chemistry, Faculty of Sciences, University of Valladolid, Valladolid, Spain
2. Department of Fundamental Physics, University of Valladolid, Valladolid, Spain
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| Abstract: | A study was made of the thermal decompositions of the hydrates of 5 neutral sulphate complexes and 5 hydroxy-sulphate complexes of uranium(IV). The hydrates did not yield corresponding stable anhydrous compounds. After dehydration, the complexes decomposed in endothermic reactions involving progressive substitution of sulphur trioxide (that is liberated) by oxygen, giving oxy-sulphates and other compunds. |
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