Compensation effect and isokinetic temperature in thermal dissociation reactions of the type Asolid ⇌ Bsolid + Cgas |
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Authors: | J Pysiak B Sabalski |
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Institution: | 1. Institute of Chemistry, Branch of Warsaw Technical University, Plock, Poland 2. Institute of Mathematics, University of Warsaw, Poland
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Abstract: | It is shown that the Zawadzki — Bretsznajder rule, compensation effect, and isokinetic temperature are simple consequences of interpretation of the Arrhenius equation as a projection correlation. It is established that such an interpretation of the Arrhenius equation allows the discrimination of the deviation factors which impart a definite (although not always simple and recognized) physical sense, to the known empirical correlation. A possibility of deriving new correlation relationships by this method of reasoning is presented. |
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