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Stereoselective synthesis of an advanced taxusin intermediate: an application of the type 2 intramolecular Diels–Alder reaction |
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| Authors: | Markian M Stec Stephen L Gwaltney Lonnie D Burke Ha Nguyen Kenneth J Shea |
| Affiliation: | aDepartment of Chemistry, University of California, Irvine, CA 92697-2025, USA |
| Abstract: | Stereoselective synthesis of an advanced taxusin intermediate is described. The key step is the successful application of the type 2 intramolecular Diels–Alder (IMDA) reaction for the assembly of the tricyclic core of this natural product. |
| Keywords: | stereoselective synthesis type 2 (IMDA) advanced taxusin intermediate bromocyclopropane |
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