Structural characterisation of the H-bonded [MnII(OH2)2...(OCH3)2MnIII] motif: a model for resting state hydroxylic solvent coordination in M(II)-M(III) enzymes |
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| Authors: | Boisen A Hazell A McKenzie C J |
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| Institution: | Department of Chemistry, University of Southern Denmark, Campus, 5230 Odense M, Denmark. |
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| Abstract: | A mixed-valence dimanganese complex with two water ligands bound to the Mn(II) ion and two methoxide ligands bound to the Mn(III) ion in a H-bonded arrangement has been structurally characterised and models possible resting state water/hydroxide coordination in purple acid phosphatases. |
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