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Alkane oxidation by a carboxylate-bridged dimanganese(III) complex
Authors:Blay G  Fernández I  Giménez T  Pedro J R  Ruiz R  Pardo E  Lloret F  Muñoz M C
Affiliation:Departament de Química Orgànica, Facultat de Química, Universitat de València, 46100 Burjassot, València, Spain.
Abstract:A new manganese(II) oxamato dimer possesing an unprecedented Mn2(mu-O2CR)(mu-OH2...O2CR) core has been synthesised, structurally and magnetically characterised, and used as a catalyst for the oxidation of alkanes to alcohols and ketones by ButO2H and O2 in CH2Cl2 at rt.
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