Alkane oxidation by a carboxylate-bridged dimanganese(III) complex |
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Authors: | Blay G Fernández I Giménez T Pedro J R Ruiz R Pardo E Lloret F Muñoz M C |
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Affiliation: | Departament de Química Orgànica, Facultat de Química, Universitat de València, 46100 Burjassot, València, Spain. |
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Abstract: | A new manganese(II) oxamato dimer possesing an unprecedented Mn2(mu-O2CR)(mu-OH2...O2CR) core has been synthesised, structurally and magnetically characterised, and used as a catalyst for the oxidation of alkanes to alcohols and ketones by ButO2H and O2 in CH2Cl2 at rt. |
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