Stereoselective total synthesis of (+)-myriocin from D-mannose |
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| Authors: | Oishi T Ando K Chida N |
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| Affiliation: | Department of Applied Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi, Kohoku-ku, Yokohama 223-8522, Japan. |
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| Abstract: | The stereoselective total synthesis of myriocin 1 from D-mannose is described; the carbon framework with three contiguous chiral centers including a tetra-substituted carbon with nitrogen was effectively constructed using Overman rearrangement as the key reaction. |
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