Experimental assessment of lanthanide ion donor preference: spectroscopic and theoretical dissection of static charge and dynamic polarisation contributions to axial ligation in a C4-symmetric chiral europium complex |
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Authors: | Bruce J I Parker D Tozer D J |
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Institution: | Department of Chemistry, University of Durham, South Road, Durham, UK DH1 3LE. david.parker@durham.ac.uk |
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Abstract: | Measurements of the equilibrium constants for ligand exchange (MeCN, 295 K) involving the axial donor in a C4-symmetric, mono-capped, square antiprismatic cationic Eu complex, supported by calculations based on an electrostatic perturbation model, have been interpreted in terms of a predominant ligand polarisation interaction defined by observation of the hypersensitive delta J = 2 normalised emission intensity, in association with measurements correlating delta J = 1 band splitting and 1H NMR dipolar shifts that vindicate Bleaney's theory of magnetic anisotropy. |
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