Revision of the absolute configuration of the tricyclic sesquiterpene (+)-kelsoene by chemical correlation and enantiospecific total synthesis of its enantiomer |
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| Authors: | Fietz-Razavian S Schulz S Dix I Jones P G |
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| Institution: | Institut für Organische Chemie, Technische Universit?t Braunschweig, Hagenring 30, D-38108, Braunschweig, Germany. |
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| Abstract: | The absolute configuration of the recently identified sesquiterpene (+)-kelsoene was revised by chemical correlation with (R)-(+)-pulegone; the correct structure is (1R,2S,5R,6R,7R,8S)-2,8-dimethyl-6-(1-methylethenyl)tricyclo5.3.0.0 (2,5)]decane. |
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