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Intramolecular addition of acyl radicals to alpha-substituted vinylogous carbonates: demonstrating the effect of ring size on acyclic stereocontrol
Authors:Evans P A  Raina S  Ahsan K
Affiliation:Department of Chemistry, Indiana University, Bloomington, IN 47405, USA. paevans@indiana.edu
Abstract:The level of stereocontrol obtained in the reduction of the free radical derived from the intramolecular addition of an acyl radical to an alpha-branched vinylogous carbonate is dependent upon the ring-size of the cyclic ether.
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