Synthesis and properties of a new family of phosphorus- and nitrogen-containing ionenes |
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Authors: | V L Mikhailenko V N Kizhnyaev S I Verkhoturova K A Apartsin N K Gusarova E G Grigor’ev B A Trofimov |
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Institution: | 2. Irkutsk State University, ul. Karla Marksa 1, Irkutsk, 664003, Russia 1. Favorsky Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia 3. Irkutsk Scientific Center of Surgery and Traumatology, ul. Bortsov Revolutsii 1, Irkutsk, 664003, Russia
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Abstract: | Polyquaternization reactions of bis2-(4-pyridyl)ethyl]phenylethylphosphine oxide and tris2-(4-pyridyl)ethyl]phosphine oxide with 1,4-dibromobutane were implemented for the first time to give linear (water-soluble) and cross-linked (limitedly water swelling), respectively, representatives of new phosphorus- and nitrogen-containing ionenes. The synthesized linear ionenes react with heparin and polyacrylic acid yielding water-insoluble polyelectrolyte complexes. |
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