Stoichiometric Reduction of CO(2) to CO by Aluminum-Based Frustrated Lewis Pairs |
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| Authors: | Ménard Gabriel Stephan Douglas W |
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| Affiliation: | Department of Chemistry, University of Toronto, 80 St. George St. Toronto Ontario, M5S 3H6 (Canada) http://www.chem.utoronto.ca/staff/DSTEPHAN. |
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| Abstract: | Reducing frustration: The reaction of Mes(3) P(CO(2) )(AlI(3) )(2) in the presence of a CO(2) atmosphere results in the formation of Mes(3) P(CO(2) )(O(AlI(2) )(2) )(AlI(3) ) and [Mes(3) PI][AlI(4) ] (Mes=2,4,6-Me(3) C(6) H(2) ) with the evolution of CO. |
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| Keywords: | aluminum carbon dioxide carbon monoxide frustrated Lewis pairs reduction |
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