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Cyclopropanation with gold(I) carbenes by retro-Buchner reaction from cycloheptatrienes |
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| Authors: | Solorio-Alvarado César R Wang Yahui Echavarren Antonio M |
| Affiliation: | Institute of Chemical Research of Catalonia (ICIQ), Av. Pai?sos Catalans 16, 43007 Tarragona, Spain. |
| Abstract: | Cationic gold(I) promotes the retro-Buchner reaction of 7-substituted 1,3,5-cycloheptatrienes, leading to gold(I) carbenes that cyclopropanate alkenes. |
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