FeCl3/NaI-catalyzed allylic C-H oxidation of arylalkenes with a catalytic amount of disulfide under air |
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| Authors: | Huang Deshun Wang Haining Xue Fazhen Shi Yian |
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| Affiliation: | Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. |
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| Abstract: | This paper describes a FeCl(3)/NaI-catalyzed formal allylic C-H oxidation of arylalkenes using a catalytic amount of disulfide with BnOH and 4-nitroaniline as nucleophiles and air as oxidant to form the corresponding allyl ethers and amines. A possible reaction mechanism has been proposed. |
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