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STRUCTURAL EVIDENCES OF Ru (H)_2(H_2) (PPh_3)_3 AT LOW TEMPERATURE
摘    要:FTIR spectrum at liquid nitrogen temperature and IH NMR ofair-sensitive polyhydride Ru(H)_2(H_2)(PPh_3)_3 have been measured for the firsttime. It is found that a fluxional process happens at room temperature, butthe structure of Ru(H)_2(H_2)(PPh_3)_3 with non-equivalent hydrogens isdiscernible at low temperature.

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