| 乙炔在铜/石墨阴极上的电催化还原加氢和电引发聚合 |
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| 引用本文： | 钟传建,张朝炎,严兴国,许丁友,王仲权. 乙炔在铜/石墨阴极上的电催化还原加氢和电引发聚合[J]. 无机化学学报, 1985, 1(1): 113-121 |
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| 作者姓名： | 钟传建 张朝炎 严兴国 许丁友 王仲权 |
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| 作者单位： | 厦门大学化学系, 物理化学研究所,厦门大学化学系, 物理化学研究所,厦门大学化学系, 物理化学研究所,厦门大学化学系, 物理化学研究所,厦门大学化学系, 物理化学研究所 |
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| 基金项目： | 中国科学院科学基金资助课题 |
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| 摘 要： | 采用恒电位电解方法,分别在酸性和碱性两种饱和乙炔的水介质中,探讨了乙炔在铜/石墨阴极上(石墨上电沉积铜和石墨一铜层状嵌入物)的电催化还原和电引发聚合行为。电极对乙炔还原成乙烯表现较高活性和很高选择性(～99%,对气相产物)。对电极上活性组份Cu0(或Cu1)与乙炔分子可能发生的σ—π活化作用和加氢方式进行了讨论。本文还运用现场与非现场Raman光谱技术,考察了在乙快还原的同时,电极表面上形成聚乙炔复盖物的情况,提出了一种电引发聚合机理,能较好地解释实验事实。
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| 关 键 词： | 乙炔 加氢 铜/石墨电极 电催化还原 电引发聚合 |
| 收稿时间： | 1985-05-06 |
ELECTROCATALYTIC REDUCTION AND ELECTROINITIATED POLYMERIZATION OF ACETYLENE ON COPPER/GRAPHITE ELECTRODES |
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| Zbong Chuanjian,Zhang Chaoyan,Yan Xingguo,Xi Dingyou and Wang Zhongquan. ELECTROCATALYTIC REDUCTION AND ELECTROINITIATED POLYMERIZATION OF ACETYLENE ON COPPER/GRAPHITE ELECTRODES[J]. Chinese Journal of Inorganic Chemistry, 1985, 1(1): 113-121 |
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| Authors: | Zbong Chuanjian Zhang Chaoyan Yan Xingguo Xi Dingyou Wang Zhongquan |
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| Affiliation: | Department of Chemistry and Institute of Physical Chemistry, Xiamen University,Department of Chemistry and Institute of Physical Chemistry, Xiamen University,Department of Chemistry and Institute of Physical Chemistry, Xiamen University,Department of Chemistry and Institute of Physical Chemistry, Xiamen University and Department of Chemistry and Institute of Physical Chemistry, Xiamen University |
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| Abstract: | |
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| Keywords: | acetylene copper/graphite electrode electrocatalytic reduction elect reinitiated polymerization hydrogenation |
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